| 20162206 |
Fernandez-Anca D, Garcia-Seijo MI, Garcia-Fernandez ME: Tripodal polyphosphine ligands as inductors of chelate ring-opening processes in mononuclear palladium (II) and platinum (II) compounds. Dalton Trans. 2010 Mar 7;39(9):2327-36. Epub 2010 Jan 18.
The reaction of NP (3) (tris [2-(diphenylphosphino) ethyl] amine and PP (3) (tris [2-(diphenylphosphino) ethyl] phosphine) with the five-coordinate complexes [PdCl (NP (3))] Cl (1) and [MX (PP (3))] X [M = Pd: X = Cl (2), Br (3), I (4); M = Pt: X = Cl (5), Br (6), I (7)], respectively, followed by (31) P{(1) H}NMR when X = Cl, led to the formation of unprecedented four-coordinate halides in a 1 : 2 metal to ligand ratio, [M (AP (3))(2)] X (2) [A = N, M = Pd: X = Cl (8); A = P, M = Pd: X = Cl (9), Br (10), I (11); A = P, M = Pt: X = Cl (12), Br (13), I (14)], containing reactive dangling phosphorus. |
31(0,1,1,1) |
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