| 1445242 |
Chai CL, Loughlin WA, Lowe G: The stereochemical course of sulphuryl transfer catalysed by arylsulphatase II from Aspergillus oryzae. Biochem J. 1992 Nov 1;287 ( Pt 3):805-12.
Phenyl [(R)-16O,17O,18O] sulphate was synthesized and used to study the stereochemical course of sulphuryl transfer to p-cresol catalysed by arylsulphatase II from Aspergillus oryzae. The reaction was shown to proceed with retention of configuration at the sulphur atom, providing evidence for the involvement of a sulpho-enzyme intermediate on the reaction pathway. |
2(0,0,0,2) |