| 15186167 |
Lo WY, Lam CH, Yam VW, Zhu N, Cheung KK, Fathallah S, Messaoudi S, Le Guennic B, Kahlal S, Halet JF: Synthesis, photophysics, electrochemistry, theoretical, and transient absorption studies of luminescent copper (I) and silver (I) diynyl complexes. J Am Chem Soc. 2004 Jun 16;126(23):7300-10.
X-ray crystal structures of [Cu3 (micro-dppm) 3 (micro3-eta1-C triple bond CC triple bond CPh) 2] PF6 and [Cu3 (micro-dppm) 3 (micro3-eta1-C triple bond CC triple bond CH) 2] PF6.. A series of soluble trinuclear copper (I) and silver (I) complexes containing bicapped diynyl ligands, [M (3)(micro-dppm)(3)(micro (3)-eta (1)-C triple bond CC triple bond CR)(2)] PF (6) (M = Cu, R = Ph, C (6) H (4)-CH (3)-p, C (6) H (4)-OCH (3)-p, (n) C (6) H (13), H; M = Ag, R = Ph, C (6) H (4)-OCH (3)-p), has been synthesized and their electronic, photophysical, and electrochemical properties studied. The X-ray crystal structures of [Cu (3)(micro-dppm)(3)(micro (3)-eta (1)-C triple bond CC triple bond CPh)(2)] PF (6) and [Cu (3)(micro-dppm)(3)(micro (3)-eta (1)-C triple bond CC triple bond CH)(2)] PF (6) have been determined. |
32(0,1,1,2) |