| 17919679 |
Wang L, Wang S, Yuan Q: Removal of carbon disulfide via coupled reactions on a bi-functional catalyst: experimental and modeling results. Chemosphere. 2007 Nov;69(11):1689-94. Epub 2007 Oct 4.
A mathematical model describing the rate of carbon disulfide (CS (2)) removal due to coupled reactions has been developed. Kinetic studies were carried out in a fixed bed reactor under atmospheric pressure and a range of temperatures (85-125 degrees C). The effects of flow rate, CS (2) inlet concentration, temperature and relative humidity were analyzed. A kinetic model based on axial dispersion, external and internal mass-transfer resistances, as well as effects of S deposition on the inner-face of the catalyst was in agreement with the CS (2) experimental breakthrough curves. The mathematical model can be used for process design and scale up of similar systems. |
33(0,1,1,3) |