16408980 |
Wang GW, Li JX, Li YJ, Liu YC: Novel reactions of [60] fullerene with amino acid esters and carbon disulfide. J Org Chem. 2006 Jan 20;71(2):680-4. [reaction: see text] Novel reactions of C60 with amino acid ester hydrochlorides and CS2 in the presence of Et3N affording fullerene derivatives 2 and 3 containing biologically active amino acids, thioamide, and thiourea units have been investigated. The thioamide groups in compounds 2 are sensitive to moisture and can easily be hydrolyzed to amide groups. |
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