Protein Information

Name complex is
Synonyms 39kD; CI 39kD; Complex I; Complex I 39kD; NADH dehydrogenase (ubiquinone) Fe S protein 2 like; NADH ubiquinone oxidoreductase 39 kDa subunit mitochondrial; NADH ubiquinone oxidoreductase 39 kDa subunit; NDUFA 9…

Compound Information

Name OCH
CAS 2,3,4,4,5,5,6,6-octachloro-2-cyclohexen-1-one

Reference List

PubMed Abstract RScore(About this table)
19055396 Lin T, Zhang W, Wang L: Complex formation between anisole and boron trifluoride: structural and binding properties. J Phys Chem A. 2008 Dec 25;112(51):13600-8.


The calculated binding energy of the 1:1 complex is close to the experimental heat of formation, which suggests that the 1:1 complexes are the most likely species in the C (6) H (5) OCH (3) and BF (3) mixture.
1(0,0,0,1) Details
11666327 Wang D, Angelici RJ: Effects of Cyclopentadienyl and Phosphine Ligands on the Basicities and Nucleophilicities of Cp'Ir (CO)(PR (3)) Complexes. Inorg Chem. 1996 Feb 28;35(5):1321-1331.


Basicities of the series of complexes CpIr (CO)(PR (3)) [PR (3) = P (p-C (6) H (4) CF (3))(3), P (p-C (6) H (4) F)(3), P (p-C (6) H (4) Cl)(3), PPh (3), P (p-C (6) H (4) CH (3))(3), P (p-C (6) H (4) OCH (3))(3), PPh (2) Me, PPhMe (2), PMe (3), PEt (3), PCy (3)] have been measured by the heat evolved (DeltaH (HM)) when the complex is protonated by CF (3) SO (3) H in 1,2-dichloroethane (DCE) at 25.0 degrees C.
1(0,0,0,1) Details
11670992 Thomas SM, Bertrand JA, Occelli ML, Huggins F, Gould SA: Microporous Montmorillonites Expanded with Alumina Clusters and M [(&mgr;-OH) Cu (&mgr;-OCH (2) CH (2) NEt (2))](6)(ClO (4))(3), (M = Al, Ga, and Fe), or Cr [(&mgr;-OCH (3))(&mgr;-OCH (2) CH (2) NEt (2)) CuCl](3) Complexes. Inorg Chem. 1999 May 3;38(9):2098-2105.


In contrast, the intermediate Al (13)-PILC structure is least affected when the more stable Cr complex is used.
1(0,0,0,1) Details
20163106 Semeniuc RF, Reamer TJ, Blitz JP, Wheeler KA, Smith MD: Functionalized O-alkyldithiocarbonates: a new class of ligands designed for luminescent heterometallic materials. Inorg Chem. 2010 Mar 15;49(6):2624-9.

Using a Ni (II) dithiophosphonate linker, the heterometallic {[CH (3) OCH (2) CH (2) OP (An) S (2)](2) Ni}[4-PyCH (2) OCS (2) Re (bipy)(CO)(3)](2) complex is obtained, through the coordination of two pyridine groups to the Ni (II) center.
6(0,0,1,1) Details
15950386 Tsuchiya K, Akai K, Tokumura A, Abe S, Tamaki T, Takiguchi Y, Fukuzawa K: Oxygen radicals photo-induced by ferric nitrilotriacetate complex. . Biochim Biophys Acta. 2005 Aug 30;1725(1):111-9.


Taken together, these results indicate that the iron (III)-NTA complex is spontaneously reduced to the iron (II)-NTA complex by light under acidic to neutral pH, and in turn transfers an electron to molecular oxygen to form ROS.
1(0,0,0,1) Details
19588963 Korobkov I, Gorelsky S, Gambarotta S: Reduced uranium complexes: synthetic and DFT study of the role of pi ligation in the stabilization of uranium species in a formal low-valent state. J Am Chem Soc. 2009 Aug 5;131(30):10406-20.


The configuration of the ligand system in this complex is similar to that in 1, with the same type of arrangement of the central phenyl ring.
1(0,0,0,1) Details
17419054 Toba T, Murata K, Nakanishi K, Takahashi B, Takemoto N, Akabane M, Nakatsuka T, Imajo S, Yamamura T, Miyake S, Annoura H: Minimum structure requirement of immunomodulatory glycolipids for predominant Th2 cytokine induction and the discovery of non-linear phytosphingosine analogs. Bioorg Med Chem Lett. 2007 May 15;17(10):2781-4. Epub 2007 Mar 3.

Analogs of immunomodulatory glycolipid OCH (2) were prepared and minimum structure requirement to exhibit equivalent profiles was disclosed.
Molecular modeling of 2/hCD1d complex based on the crystal structure of alpha-GalCer (1)/hCD1d complex is also described.
1(0,0,0,1) Details
15672193 Barfod R, Eriksen J, Golding BT, Hammershoi A, Jacobsen TA, Langkilde A, Larsen S, Monsted O, Sargeson AM, Sorensen HO: Facile cobalt (III) template synthesis of novel branched hexadentate polyamine monocarboxylates. Dalton Trans. 2005 Feb 7;(3):491-500. Epub 2004 Dec 21.


For n= 1, imine formation occurred exclusively at the primary amine trans to the carboxylate producing the hexadentate 11-amino-9-(2-aminoethyl)-3,6,9-triazaundeca-5-enoato (tren-enimgly-) complex, i-[Co (tren-enimgly)] Cl2.3.5H2O.
1(0,0,0,1) Details
18095674 Scheifele Q, Riplinger C, Neese F, Weihe H, Barra AL, Juranyi F, Podlesnyak A, Tregenna-Piggott PL: Spectroscopic and theoretical study of a mononuclear manganese (III) complex exhibiting a tetragonally compressed geometry. Inorg Chem. 2008 Jan 21;47(2):439-47. Epub 2007 Dec 21.


The complex is of particular interest given the biochemical activity and the unusual stereochemistry distinguished by a rare example of a tetragonally compressed octahedron and a pronounced angular distortion imposed by the tetradentate tripodal bpia ligand.
1(0,0,0,1) Details
14678004 Tamura H, Yamazaki H, Sato H, Sakaki S: Iridium-catalyzed borylation of benzene with diboron. J Am Chem Soc. 2003 Dec 24;125(51):16114-26.


From these results, it should be clearly concluded that the iridium (III) tris (boryl) complex is an active species and an unusual iridium (V) species is involved as a key intermediate in the reaction.
1(0,0,0,1) Details