| 15306893 |
Shimakoshi H, Tokunaga M, Baba T, Hisaeda Y: Photochemical dechlorination of DDT catalyzed by a hydrophobic vitamin B12 and a photosensitizer under irradiation with visible light. Chem Commun. 2004 Aug 21;(16):1806-7. Epub 2004 Jul 28.
Dechlorination of 1,1-bis (4-chlorophenyl)-2,2,2-trichloroethane (DDT) was catalyzed by a hydrophobic vitamin B (12), heptamethyl cobyrinate perchlorate, with a visible light irradiation system containing a [Ru (ii)(bpy)(3)] Cl (2) photosensitizer, and the hydrophobic vitamin B (12) showed high catalytic efficiency and stability during the reaction. |
81(1,1,1,1) |