Protein Information

Name OTf 3
Synonyms OCT3; OCT4; OTF 3; OTF 4; OTF3; OTF4; Oct3; Octamer binding transcription factor 3…

Compound Information

Name phosphine
CAS phosphine

Reference List

PubMed Abstract RScore(About this table)
17137383 Goossen LJ, Blanchot M, Brinkmann C, Goossen K, Karch R, Rivas-Nass A: Ru-catalyzed stereoselective addition of imides to alkynes. J Org Chem. 2006 Dec 8;71(25):9506-9.

A catalyst system formed in situ from bis (2-methylallyl) cycloocta-1,5-dieneruthenium (II) ((cod) Ru [met] 2), a phosphine, and scandium (III) trifluoromethanesulfonate (Sc (OTf) 3) was found to efficiently catalyze the anti-Markovnikov addition of imides to terminal alkynes, allowing mild and atom-economic synthesis of enimides.
31(0,1,1,1) Details
15732979 Oberbeckmann-Winter N, Morise X, Braunstein P, Welter R: Synthesis and structure of Pt (II) phosphonato-phosphine complexes and of a P,O-stabilized metal-metal-bonded Pt2Ag2 complex. Inorg Chem. 2005 Mar 7;44(5):1391-403.

New, mononuclear Pt (II) complexes containing one or two PPO ligands, [PtClMe (kappa2-PPO)] (1), [Pt{C (O) Me}Cl (kappa2-PPO)] (2), [PtMe (CO)(kappa2-PPO)] OTf (3 x OTf), [PtMe (OTf)(kappa2-PPO)] (4), trans-[PtClMe (kappa1-PPO) 2] (5), [PtMe (kappa2-PPO)(kappa1-PPO)] BF4 (6 x BF4), [PtMe (kappa2-PPO)(kappa1-PPO)] OTf (6 x OTf), and [Pt{C (O) Me}(kappa2-PPO)(kappa1-PPO)] BF4 (7 x BF4) have been prepared and characterized.
1(0,0,0,1) Details
18578491 Teo P, Koh LL, Hor TS: Oligo- and polymeric Pd (II) and Pt (II) using pyridyl carboxylate spacers for topology control. Inorg Chem. 2008 Jul 21;47(14):6464-74. Epub 2008 Jun 26.

A change of the denticity of the phosphine does not affect the topological outcome.
The ability of these assemblies to capture cations, such as Na (+) in [Pt3Na (3-NC5H4CO2) 3 (OTf) 3 (PPh3) 6](+) through hydrogen bonding or Ag (+) in [PdAg (2-NC5H4CO2)(OTf) 2 (dppf)] through dative bonding, is described and compared.
1(0,0,0,1) Details