Name | complex is |
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Synonyms | 39kD; CI 39kD; Complex I; Complex I 39kD; NADH dehydrogenase (ubiquinone) Fe S protein 2 like; NADH ubiquinone oxidoreductase 39 kDa subunit mitochondrial; NADH ubiquinone oxidoreductase 39 kDa subunit; NDUFA 9… |
Name | chloroform |
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CAS | trichloromethane |
PubMed | Abstract | RScore(About this table) | |
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18835659 | Agrawal K, Patel KS, Shrivas K, Jain VK, Khan F: On-site determination of tin in geological and water samples using novel organic reagent with iodide. J Hazard Mater. 2009 May 15;164(1):95-8. Epub 2008 Aug 3. The Sn (IV)-I (-) complex is extracted with chloroform solution of amide (N-phenylacetamide, N-alkylacetamide, alkyl=butyl, phenyl, hexyl and octyl group) in the strong sulphuric acid solution. |
6(0,0,1,1) | Details |
18970354 | Khuhawar MY, Arain GM: Liquid chromatographic determination of The complex is extracted in chloroform together with palladium (II), tin (II) and iron (III) and eluted and separated completely from Kromasil 100 C-18, 10mum (25cmx4.6mm i.d.) column with methanol:water:acetonitrile (60:30:10, v/v/v) with a flow rate of 1ml/min. |
in petroleum oils and mineral ore samples using 2-acetylpyridne-4-phenyl-3-thiosemicarbazone as derivatizing reagent. Talanta. 2006 Jan 15;68(3):535-41. Epub 2005 Jun 20.6(0,0,1,1) | Details |
19914125 | Fakhroo AA, Bazzi HS, Mostafa A, Shahada L: Synthesis, spectroscopic and thermal structural investigations of the charge-transfer complexes formed in the reaction of 1-methylpiperidine with sigma- and pi-acceptors. Spectrochim Acta A Mol Biomol Spectrosc. 2010 Jan;75(1):134-41. Epub 2009 Oct 6. The reactions of the electron donor 1-methylpiperidine (1MP) with the pi-acceptors 7,7,8,8-tetracyanoquinodimethane (TCNQ), tetracyanoethylene (TCNE), 2,3-dichloro-5,6-dicyano- (DDQ), 2,3,5,6-tetrachloro- (chloranil=CHL) and (I (2)) were studied spectrophotometrically in chloroform at room temperature. Based on the obtained data, the formed charge-transfer complexes were formulated as [(1MP)(TCNE)(2)], [(1MP)(DDQ)].H (2) O, [(1MP)(CHL)] and [(1MP) I] I (3), while in the case of 1MP-TCNQ reaction, a short-lived CT complex is formed followed by rapid N-substitution by TCNQ forming the final reaction products 7,7,8-tricyano-8-piperidinylquinodimethane (TCPQDM). |
1(0,0,0,1) | Details |
19382591 | Boison J, Lee S, Gedir R: Analytical determination of virginiamycin drug residues in edible porcine tissues by LC-MS with confirmation by LC-MS/MS. J AOAC Int. 2009 Jan-Feb;92(1):329-39. VMY in the eluate is partitioned into chloroform and the aqueous upper layer is removed by aspiration. |
0(0,0,0,0) | Details |
17431527 | Chevrot G, Schurhammer R, Wipff G: Synergistic effect of dicarbollide anions in liquid-liquid extraction: a molecular dynamics study at the The remaining CCD (-) anions adsorb at the interface, but are less surface active than at the chloroform interface. It is found that when the CCD (-)'s are concentrated enough, the complex is extracted to the phase. |
-water interface. Phys Chem Chem Phys. 2007 Apr 28;9(16):1991-2003. Epub 2007 Feb 23.1(0,0,0,1) | Details |
19320514 | Mukhopadhyay A, Mukherjee M, Pandey P, Samanta AK, Bandyopadhyay B, Chakraborty T: Blue shifting C-H..O complexes between chloroform and small cyclic ketones: ring-size effects on stability and spectral shifts.. J Phys Chem A. 2009 Apr 2;113(13):3078-87. NBO analysis reveals that the blue shifting of the nu (C-H) transition in a complex is the net effect of hyperconjugation and repolarization/rehybridization of the bond under the influence of the electric field of carbonyl |
bonded 1(0,0,0,1) | Details |
18177020 | Pedersen MO, Pham L, Steensgaard DB, Miller M: A reconstituted light-harvesting complex from the green bacterium Chlorobium tepidum containing CsmA and bacteriochlorophyll a. Biochemistry. 2008 Feb 5;47(5):1435-41. Epub 2008 Jan 5. This CsmA-BChl a complex is located in the chlorosome baseplate with the hydrophilic C-terminal part of CsmA in contact with the FMO protein. Isolated chlorosomes were lyophilized and extracted with chloroform/ (1:1, v/v). |
1(0,0,0,1) | Details |
18681484 | Li Z, Tao J, Lu X, Zhu Y, Xia Y: Facile synthesis of ultrathin Au nanorods by aging the AuCl (oleylamine) complex with amorphous Fe nanoparticles in chloroform. Nano Lett. 2008 Sep;8(9):3052-5. Epub 2008 Aug 6. This growth mechanism is different from the mechanism recently reported for ultrathin Au nanowires (ref ), where the [AuCl (oleylamine)] complex is assembled into polymer chains followed by reduction to form wires, although the template effect of oleylamine for the formation of ultrathin Au nanorods cannot be completely ruled out. |
1(0,0,0,1) | Details |
18975819 | Cui HX, Chen JM, Zhou HD: [Study on spectroscopic properties of Eu and Tb mixed solid complexes with a diamide ligand]. Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Aug;28(8):1856-61. In the present work, Eu (NO3) 3 and Tb (NO3) 3 complexes with a diamide ligand 1,6-bis [(2'-benzylaminoformyl) phenoxyl] hexane (L) were prepared in the solution of chloroform and ethyl When the content of Eu complex is large, this peak is near to the position of the 5 D0--> 7 F1 transition, but when the content of Tb complex is large, it is near to the position of the 5 D4--> 7 F4 transition. |
1(0,0,0,1) | Details |
18571390 | Posa M, Guzsvany V, Csanadi J, Kevresan S, Kuhajda K: Formation of complexes between bile acids and lidocaine in the lidocaine transfer from an aqueous phase to chloroform. Eur J Pharm Sci. 2008 Aug 7;34(4-5):281-92. Epub 2008 May 9. It was found that a prerequisite for forming such a complex is the existence of at least two OH groups or one OH group and one keto group in the bile acid molecule at an appropriate mutual distance. |
-bonded 1(0,0,0,1) | Details |
17764247 | Hippler M: Quantum chemical study and infrared spectroscopy of Molecular association of chloroform with is studied by high-level quantum chemical calculations including correlated MP2 and CCSD (T) calculations with basis sets up to6-311++G (d,p) and counterpoise corrected energies, geometries, and frequencies. Based on these predictions, the complex is observed by infrared spectroscopy in the gas phase at room temperature. |
-bonded CHCl (3)-NH (3) in the gas phase. J Chem Phys. 2007 Aug 28;127(8):084306.1(0,0,0,1) | Details |
17728870 | Kildahl-Andersen G, Naess SN, Aslaksen PB, Anthonsen T, Liaaen-Jensen S: Studies on the mechanism of the Carr-Price blue colour reaction. Org Biomol Chem. 2007 Sep 21;5(18):3027-33. Epub 2007 Aug 9. The classical Carr-Price reaction between and the Lewis acid SbCl (3) in saturated chloroform solution was reinvestigated by VIS, NMR, EPR, dynamic light scattering and chemical quenching. The VIS data support structural similarity of the blue Carr-Price product with the delocalized anhydroretinylic cation, and a detailed structure of the antimony complex is evaluated. |
1(0,0,0,1) | Details |
17419092 | Ansari AA, Hussain HA, Iftikhar K: Optical absorption spectroscopic studies on holmium (III) complexes with beta-diketone and heterocyclic amines: the environment effect on 4f-4f hypersensitive transitions. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Dec 31;68(5):1305-12. Epub 2007 Feb 13. The optical absorption spectra of [Ho (acac)(3)(H (2) O)(2)].H (2) O, [Ho (acac)(3) phen] and [Ho (acac)(3) bpy] (where acac is the anion of acetylacetone; phen is 1,10-phenanthroline and bpy is 2,2'-bipyridyl) complexes in the visible region, in a series of non-aqueous solvents chloroform, acetonitrile and have been analyzed. The TGA analyses showed that the phen complex is thermally more stable over its bpy analogue. |
1(0,0,0,1) | Details |
18968014 | Gavazov K, Simeonova Z, Alexandrov A: Extraction spectrophotometric determination of aluminium alloys using pyridyl azo resorcinol (PAR) and iodo-nitro-tetrazolium chloride (INT). Talanta. 2000 Jun 30;52(3):539-44. They are based on the formation and subsequent extraction into chloroform of the ternary ion association complex of V (V) with PAR and INT in the presence of CDTA and NH (4) F as masking agents. Maximum absorbance of the extracted complex is at 560 nm. |
in natural waters and 1(0,0,0,1) | Details |
20334425 | Mukhopadhyay A, Pandey P, Chakraborty T: Blue- and Red-Shifting CH..O Complexes between Haloforms and Ethers: Correlation of Donor nu (C-H) Spectral Shifts with C-O-C Angular Strain of the Acceptors.. J Phys Chem A. 2010 Mar 24. The optimized structures of the two complexes are largely different with respect to the intermolecular orientational parameters at the bonding sites, and similar behavior is also predicted for the two chloroform complexes. The predicted Deltanu (C-H) of each complex is analyzed with respect to the IR spectral shift measured by van der Veken and coworkers in cryosolutions of inert gases. (27, 31, 32) The disagreement found between the measured and calculated IR shifts is interpreted to be the outcome of deformation of the complex geometries along shallow binding potential energy surfaces owing to solvation in the liquefied inert gases. |
Bonded 1(0,0,0,1) | Details |
17989801 | Chevrot G, Schurhammer R, Wipff G: Molecular dynamics study of dicarbollide anions in nitrobenzene solution and at its aqueous interface. Phys Chem Chem Phys. 2007 Nov 28;9(44):5928-38. Epub 2007 Sep 28. The remaining CCD (-) anions adsorb at the interface, but are less surface active than at the chloroform interface. It is found that in the absence of CCDs, the complex is trapped at the interface, while when the CCDs are concentrated enough, the complex is extracted to the nitrobenzene phase. |
1(0,0,0,1) | Details |
19373608 | Ding H, Han C, Guo D, Chin YW, Ding Y, Kinghorn AD, D'Ambrosio SM: Selective induction of apoptosis of human oral cancer cell lines by avocado extracts via a ROS-mediated mechanism. Nutr Cancer. 2009;61(3):348-56. Previously we reported that phytochemicals extracted from avocado meat into a chloroform partition (D003) selectively induced apoptosis in cancer but not normal, human oral epithelial cell lines. D003 increased ROS levels via mitochondrial complex I in the electron transport chain to induce apoptosis. |
1(0,0,0,1) | Details |
17622411 | Sieffert N, Wipff G: The effect of a solvent modifier in the cesium extraction by a calix [4] arene: a molecular dynamics study of the oil phase and the oil-water interface. Phys Chem Chem Phys. 2007 Jul 28;9(28):3763-75. Epub 2007 May 31. It is shown that adding cs3 to a chloroform phase improves the solvation of all partners of the extraction system, i.e. the free calixarene ligand L, its LCs (+) complex and its counterion. |
0(0,0,0,0) | Details |