Name | COCH |
---|---|
Synonyms | COCH; COCH 5B2; COCH5B2; Cochlin; Cochlin precursor; DFNA 9; DFNA31; DFNA9… |
Name | OCH |
---|---|
CAS | 2,3,4,4,5,5,6,6-octachloro-2-cyclohexen-1-one |
PubMed | Abstract | RScore(About this table) | |
---|---|---|---|
19584101 | Pazynina G, Sablina M, Mayzel M, Nasonov V, Tuzikov A, Bovin N: Chemical synthesis of 6 - and 6 (Gal)-O-sulfated SiaLe (X) tetrasaccharides in spacer-armed form. Glycobiology. 2009 Oct;19(10):1078-81. Epub 2009 Jul 7. The sulfated SiaLe (x) derivative was modified at the spacer group to give 6 ((Gal))-O-Su-SiaLe (x)- OCH (2) CH (2) CH (2) NH-COCH (2) CH (2) C [triple bond] CH, convenient for "click chemistry" mode conjugation with an azido carrier, particularly, for the synthesis of an immunogen. |
31(0,1,1,1) | Details |
15154812 | Wei QH, Yin GQ, Zhang LY, Shi LX, Mao ZW, Chen ZN: Luminescent Ag i-Cu i heterometallic hexa-, octa-, and hexadecanuclear alkynyl complexes. Inorg Chem. 2004 May 31;43(11):3484-91. Self-assembly reaction between (MCCC (6) H (4) COCH (3)-4)(n) and [M'(2)(mu-Ph (2) PCH (2) PPh (2))(2)(MeCN)(2)](ClO (4))(2), however, gave heterohexadecanuclear complex [Ag (6) Cu (2)(micro-Ph (2) PCH (2) PPh (2))(3)(CCC (6) H (4) COCH (3)-4)(6)](2)(ClO (4) )(4) (7). |
2(0,0,0,2) | Details |
11559172 | Singh RP, Majumder U, Shreeve JM: Nucleophilic di- and tetrafluorination of dicarbonyl compounds. J Org Chem. 2001 Sep 21;66(19):6263-7. Reactions of beta-diketones, R (3) COCH (2) COR (4) (R (3) = R (4) = Ph; R (3) = R (4) = Me; R (3) = Me, R (4) = Ph) (4e-g), with Deoxofluor in the presence of a catalytic amount of HF led to the formation of difluoroalkenones as a mixture of E (5e-g) and Z (6e-g) isomers in good yield. |
1(0,0,0,1) | Details |
17589872 | Yamnitz CR, Gokel GW: Synthetic, biologically active amphiphilic peptides. Chem Biodivers. 2007 Jun;4(6):1395-412. The main focus of this article lies on the family of synthetic anion binders (SATs) of the general structure (R (1))(2) N-COCH (2) OCH (2) CO-(Aaa)(n)-OR (3). |
2(0,0,0,2) | Details |
18688484 | You L, Li R, Gokel GW: Anion transport properties of amine and amide-sidechained peptides are affected by charge and phospholipid composition. Org Biomol Chem. 2008 Aug 21;6(16):2914-23. Epub 2008 Jun 16. Four synthetic anion transporters (SATs) having the general formula (n-C (18) H (37))(2) N-COCH (2) OCH (2) CO-(Gly)(3) Pro- (epsilon-N-R)-(Gly)(2)-O -n-C (7) H (15) were prepared and studied. |
1(0,0,0,1) | Details |
12919040 | Rayabarapu DK, Yang CH, Cheng CH: Regioselective synthesis of indenols via -catalyzed carbocyclization reaction. J Org Chem. 2003 Aug 22;68(17):6726-31. 2-Halophenyl ketones 1a-e (1a, o-IC (6) H (4) COCH (3)) undergo carbocyclization with alkyl propiolates (2a, CH (3)(CH (2))(4) C [triple bond] CCO (2) CH (3); 2b, TMSC [triple bond] CCO (2) Et 2c, CH (3) C [triple bond] CCO (2) CH (3); 2d, CH (3) OCH (2) C [triple bond] CCO (2) CH (3); 2e, CH (3)(CH (2))(3) C [triple bond] CCO (2) CH (3); 2f, PhC [triple bond] CCO (2) CH (3); and 2g, (CH (3))(3) C [triple bond] CCO (2) CH (3)) in the presence of Ni (dppe) Br (2) and zinc powder in acetonitrile at 80 degrees C to afford the corresponding indenol derivatives 3a-m with remarkable regioselectivity in good to excellent yields. |
1(0,0,0,1) | Details |
17637962 | Ferdani R, Li R, Pajewski R, Pajewska J, Winter RK, Gokel GW: Transport of and carboxyfluorescein through phospholipid vesicle membranes by heptapeptide amphiphiles. Org Biomol Chem. 2007 Aug 7;5(15):2423-32. Epub 2007 Jun 25. Seven synthetic anion transporters (SAT) of the general form R (2) N-COCH (2) OCH (2) CO-(Gly)(3)-Pro-(Gly)(3)-OR' were prepared. |
1(0,0,0,1) | Details |
19633728 | Djedovic N, Ferdani R, Harder E, Pajewska J, Pajewski R, Weber ME, Schlesinger PH, Gokel GW: The C- and N-Terminal Residues of Synthetic Heptapeptide Ion Channels Influence Transport Efficacy Through Phospholipid Bilayers. New J Chem. 2005 Jan 1;29(2):291-305. The synthetic peptide, R (2) N-COCH (2) OCH (2) CO-Gly-Gly- -Gly-Gly-Gly-OR', was shown to be selective for Cl (-) over K (+) when R is n-octadecyl and R' is benzyl. |
1(0,0,0,1) | Details |
19169373 | Ferdani R, Pajewski R, Djedovic N, Pajewska J, Schlesinger PH, Gokel GW: Anion Transport in Liposomes Responds to Variations in the Anchor Chains and the Fourth Amino Acid of Heptapeptide Ion Channels. New J Chem. 2005;29:673-280. and carboxyfluorescein release from phospholipid vesicles was studied with the result that C (10) H (21) N (C (2) H (5)) COCH (2) OCH (2) CO-NH-(Gly)(3) (Gly)(3)-OCH (2) Ph was the most active. |
1(0,0,0,1) | Details |
14982463 | Ochiai M, Lin YS, Yamada J, Misawa H, Arai S, Matsumoto K: Reactions of a platinum (III) dimeric complex with alkynes in water: novel approach to alpha-aminoketone, alpha-iminoketone, and alpha,beta-diimine via ketonyl-Pt (III) dinuclear complexes. J Am Chem Soc. 2004 Mar 3;126(8):2536-45. Internal alkyne 2-butyne reacted with 1 to form the complex [Pt (2)(NH (3))(4)((CH (3))(3) CCONH)(2)(CH (CH (3)) COCH (3))](NO (3))(3) (12). |
1(0,0,0,1) | Details |