| 15186167 |
Lo WY, Lam CH, Yam VW, Zhu N, Cheung KK, Fathallah S, Messaoudi S, Le Guennic B, Kahlal S, Halet JF: Synthesis, photophysics, electrochemistry, theoretical, and transient absorption studies of luminescent copper (I) and silver (I) diynyl complexes. J Am Chem Soc. 2004 Jun 16;126(23):7300-10.
A series of soluble trinuclear copper (I) and silver (I) complexes containing bicapped diynyl ligands, [M (3)(micro-dppm)(3)(micro (3)-eta (1)-C triple bond CC triple bond CR)(2)] PF (6) (M = Cu, R = Ph, C (6) H (4)-CH (3)-p, C (6) H (4)-OCH (3)-p, (n) C (6) H (13), H; M = Ag, R = Ph, C (6) H (4)-OCH (3)-p), has been synthesized and their electronic, photophysical, and electrochemical properties studied. |
32(0,1,1,2) |
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| 11666239 |
Lindner E, Schreiber R, Schneller T, Wegner P, Mayer HA, Gopel W, Ziegler C: Synthesis of Polysiloxane-Bound (Ether-phosphine) palladium Complexes. Inorg Chem. 1996 Jan 17;35(2):514-525.
The compounds 2a (T (0)())(2)() and 2b (T (0)())(2)() are sol-gel processed with variable amounts (y) of Si (OEt)(4) (Q (0)()) to give the polysiloxane-bound complexes 2a (T (n)())(2)()(Q (k)())(y)(), 2b (T (n)())(2)()(Q (k)())(y)() (Table 1) {P approximately O = eta (1)-P-coordinated ether-phosphine ligand; for T (n)() and Q (k)(), y = number of condensed T type (three oxygen neighbors), Q type (four oxygen neighbors) silicon atoms; n and k = number of Si-O-Si bonds; n = 0-3; k = 0-4; 2a (T (n)())(2)()(Q (k)())(y)(), 2b (T (n)())(2)()(Q (k)())(y)() = {[M]-SiO (n)()(/2)(OX)(3)(-)(n)()}(2)[SiO (k)()(/2)(OX)(4)(-)(k)()](y)(), [M] = (Cl (2) Pd)(1/2)(Ph) P (CH (2) Do)(CH (2))(3)-, X = H, Me, Et}. |
1(0,0,0,1) |
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