Protein Information

Name Cl 2
Synonyms AMB11; MHC class I NK cell receptor; CD158E1; CD158E1/2; CD158E2; CL 11; CL 2; HLA BW4 specific inhibitory NK cell receptor…

Compound Information

Name ethylene
CAS ethene

Reference List

PubMed Abstract RScore(About this table)
19891436 Tia R, Adei E: Density functional theory study of the mechanisms of oxidation of ethylene by chromyl chloride. Inorg Chem. 2009 Dec 7;48(23):11434-43.

The formation of the epoxide precursor (Cl (2)(O) Cr-OC (2) H (4)) was found to take place via initial [2 + 2] addition of ethylene across the Cr=O bonds of CrO (2) Cl (2) to form a chromaoxetane intermediate.
18(0,0,3,3) Details
20200707 Barry NP, Edafe F, Dyson PJ, Therrien B: Anticancer activity of osmium metalla-rectangles. Dalton Trans. 2010 Mar 21;39(11):2816-20. Epub 2010 Feb 4.

A series of cationic metalla-rectangles of the general formula [(p-cymene)(4) Os (4)(OO [intersection] OO)(2)(N [intersection] N)(2)](4+) have been obtained in methanol from the dinuclear arene osmium precursors [(p-cymene)(2) Os (2)(OO [intersection] OO)(2) Cl (2)] (OO [intersection] OO = 2,5-dioxydo-1,4-benzoquinonato (dhbq), 2,5-dichloro-1,4-benzoquinonato (dcbq)) by reaction with bipyridine linkers (N [intersection] N = 4,4'-bipyridine, 1,2-bis (4-pyridyl) ethylene) in the presence of AgCF (3) SO (3).
6(0,0,1,1) Details
19789798 Zhang WZ, Han YF, Lin YJ, Jin GX: Synthesis and characterization of molecular rectangles of half-sandwich p-cymene ruthenium complexes bearing oxamidato ligands. Dalton Trans. 2009 Oct 21;(39):8426-31. Epub 2009 Aug 28.

A series of binuclear half-sandwich p-cymene ruthenium complexes bearing oxamidato ligands [(p-cymene)(2) Ru (2)(mu-N,N'-bis (aryl) oxamidato) Cl (2)] (1-3) was synthesized by the reactions of the lithium salts of oxamide with [(p-cymene) RuCl (2)](2), respectively.
Treatment of the binuclear complexes (1-3) with bidentate ligands such as 4,4'-bipyridine (4,4'-bpy) and trans-1,2-bis (4-pyridyl) ethylene (bpe) in the presence of AgOTf (OTf = CF (3) SO (3)) gave the corresponding tetranuclear complexes generally formulated as [(p-cymene)(4) Ru (4)(mu-N,N'- bis (aryl) oxamidato)(2)(mu-4,4'-bpy)(2)](OTf)(4) (4a-c) and [(p-cymene)(4) Ru (4)(mu-N,N'-bis (aryl) oxamidato)(2)(mu-bpe)(2)](OTf)(4) (5a-c) in high yields.
1(0,0,0,1) Details
19597608 Cruz AR, Zolotukhin MG, Morales SL, Cardenas J, Cedillo G, Fomine S, Salmon M, Carreon-Castro MP: Use of 4-piperidones in one-pot syntheses of novel, high-molecular-weight linear and virtually 100%-hyperbranched polymers. Chem Commun. 2009 Aug 7;(29):4408-10. Epub 2009 Jun 10.


4-Piperidone and 4-alkyl piperidones react selectively with aromatic hydrocarbons in a mixture of trifluoromethanesulfonic acid (TFSA) and CH (2) Cl (2) to give linear polymers, while N-(2-phenethyl) piperidone undergoes self-polymerization to yield virtually 100%-hyperbranched polymer.
1(0,0,0,1) Details
20297807 Boedigheimer H, Ferrence GM, Lash TD: Porphyrin on a Half-Shell! Synthesis and Characterization of Corannulenoporphyrins (dagger). J Org Chem. 2010 Mar 18.

Following cleavage of the ethyl ester moiety with KOH in ethylene glycol at 180-190 degrees C, the heptacyclic system was reacted with acetoxymethylpyrroles under mildly acidic conditions to afford tripyrranes.
Treatment of a di-tert-butyl ester tripyrrane with TFA cleaved the protective groups, and subsequent condensation with diformylpyrroles in TFA-CH (2) Cl (2), followed by oxidation with DDQ or ferric chloride, gave excellent yields of corannulenoporphyrins.
1(0,0,0,1) Details
19826726 Khamker Q, Champouret YD, Singh K, Solan GA: Bis (imino) quaterpyridine-bearing multimetallic late transition metal complexes as ethylene oligomerisation catalysts. Dalton Trans. 2009 Nov 7;(41):8935-44. Epub 2009 Sep 24.

Reactions of L (tripp) with 2.5 equivalents of MX (2) (MX (2) = CoCl (2), CoBr (2), (DME)(2) NiCl (2) and FeCl (2)) in n-butanol at 100 degrees C overnight results in self-assembly to form the paramagnetic salts [(L (tripp)) M (2) X (3)](2)[MX (4)] [M = Co, X = Cl (1a); M = Co, X = Br (1b); M = Ni, X = Cl (2); M = Fe X = Cl (3)] in moderate yield.
1(0,0,0,1) Details
19789776 Gong S, Ma H, Huang J: Zirconium and hafnium complexes supported by linked bis (beta-diketiminate) ligands: synthesis, characterization and catalytic application in ethylene polymerization. Dalton Trans. 2009 Oct 21;(39):8237-47. Epub 2009 Aug 10.

Zirconium and hafnium complexes bearing new 1,2-ethanediyl- or 1,3-propanediyl-linked bis (beta-diketiminate) ligands, [{C (n) H (2n)-(BDI (Ar))(2)}MCl (2)] (Ar = 2,6-Me (2)-C (6) H (3), 2,6-Cl (2)-C (6) H (3), 2,6-(i) Pr (2)-C (6) H (3); M = Zr, n = 2 (4a-c), n = 3 (5a-c); M = Hf, n = 2 (6b)), were synthesized via the reaction of MCl (4).2THF and one equivalent of dilithium salt of the corresponding ligand.
1(0,0,0,1) Details
19813765 Thirupathi P, Kim SS: InBr3: a versatile catalyst for the different types of Friedel-Crafts reactions. J Org Chem. 2009 Oct 16;74(20):7755-61.


Mild and efficient InBr (3)-catalyzed Friedel-Crafts alkylation of heteroaromatic or electron-rich aromatic compounds with alpha-amido sulfones at room temperature in CH (2) Cl (2) has been developed.
1(0,0,0,1) Details