| Name | PH3 |
|---|---|
| Synonyms | EDR 3; EDR3; Early development regulator 3; Early development regulatory protein 3; HPH3; Homolog of polyhomeotic 3; PH3; PHC 3… |
| Name | phosphine |
|---|---|
| CAS | phosphine |
| PubMed | Abstract | RScore(About this table) | |
|---|---|---|---|
| 16212183 | Mu QL, Song XX, Yu ZM: [Matrix-bound phosphine (PH3) distribution characteristics in the sediments of Jiaozhou Bay, China]. Huan Jing Ke Xue. 2005 Jul;26(4):135-8. |
31(0,1,1,1) | Details |
| 17428038 | Guo Y, Gu X, Zhang F, Sun BJ, Tsai MF, Chang AH, Kaiser RI: Unraveling the formation of HCPH (X2A') molecules in extraterrestrial environments: crossed molecular beam study of the reaction of carbon atoms, C (3Pj), with phosphine, PH3 (X1A1). J Phys Chem A. 2007 May 3;111(17):3241-7. Epub 2007 Apr 12. |
12(0,0,2,2) | Details |
| 19650627 | Norton DM, Mitchell EA, Botros NR, Jessop PG, Baird MC: A superior precursor for palladium (0)-based cross-coupling and other catalytic reactions. J Org Chem. 2009 Sep 4;74(17):6674-80. The easily synthesized, easily handled compound Pd (eta (3)-1-PhC (3) H (4))(eta (5)-C (5) H (5)) (II) reacts readily with mono- and bidentate tertiary phosphines to produce the corresponding bis-phosphine palladium (0) complexes in good yields; II is thus an excellent precursor, perhaps the most efficacious and reliable available, for the synthesis of palladium (0) cross-coupling catalysts. |
31(0,1,1,1) | Details |
| 16294866 | Glindemann D, Edwards M, Morgenstern P: Phosphine from rocks: mechanically driven reduction? . Environ Sci Technol. 2005 Nov 1;39(21):8295-9. An order of magnitude more phosphine (average 1982 ng PH3 kg rock and maximum 6673 ng PH3/kg rock) is released from pulverized rock samples (basalt, gneiss, granite, clay, quartzitic pebbles, or marble). |
8(0,0,1,3) | Details |
| 16390185 | Flora JW, Byers LE, Plunkett SE, Faustini DL: Residue formations of hydride polymers and oxyacids during phosphine gas fumigations of stored products. J Agric Food Chem. 2006 Jan 11;54(1):107-11. With the extent of international usage and the critical role phosphine gas (PH3) plays in commercial pest control, identification of the residual components deposited during fumigation is mandatory. |
8(0,0,1,3) | Details |
| 15601102 | Wilson HF, Warschkow O, Marks NA, Schofield SR, Curson NJ, Smith PV, Radny MW, McKenzie DR, Simmons MY: Phosphine dissociation on the Si (001) surface. Phys Rev Lett. 2004 Nov 26;93(22):226102. Epub 2004 Nov 23. Density functional calculations are performed to identify features observed in STM experiments after phosphine (PH3) dosing of the Si (001) surface. |
7(0,0,1,2) | Details |
| 17764199 | Das U, Raghavachari K, Woo RL, Hicks RF: Phosphine adsorption on the In-rich InP (001) surface: evidence of surface dative bonds at room temperature. Langmuir. 2007 Sep 25;23(20):10109-15. Epub 2007 Sep 1. We have performed density functional calculations using finite-sized cluster models to investigate the dissociative adsorption of PH3 on the In-rich InP surface. |
7(0,0,0,7) | Details |
| 16161569 | Ervin KM, Lineberger WC: Photoelectron spectroscopy of hydride anions. J Chem Phys. 2005 May 15;122(19):194303. The derived gas-phase acidity of phosphine is delta (acid) G298 (PH3) < or = 1509.7 +/- 2.1 kJ mo1 (-1). |
6(0,0,1,1) | Details |
| 16526856 | Jakubek ZJ, Bunker PR, Zachwieja M, Nakhate SG, Simard B, Yurchenko SN, Thiel W, Jensen P: A dispersed fluorescence and ab initio investigation of the X2B1 and A2A1 electronic states of the PH2 molecule. J Chem Phys. 2006 Mar 7;124(9):94306. PH2 molecules were produced in a molecular free-jet apparatus by laser vaporizing a rod in the presence of phosphine (PH3) gas diluted in helium. |
6(0,0,1,1) | Details |
| 15736879 | Roels J, Vanhaecke F, Verstraete W: Combustive approach for measuring total volatile content in landfill gas. Environ Monit Assess. 2005 Feb;101(1-3):103-16. The phosphine (PH3) content measured with GC ranged from 7.6 to 16.7 microg PH3-P/m3. |
6(0,0,1,1) | Details |
| 15709430 | Chen H, Zhou Y, Zhu J, Yang X, Lu L, Wang X: [Determination of phosphine liberated in the storage of amorphous by headspace gas chromatography]. Se Pu. 2004 Jul;22(4):442-4. It was found that water was the most important agent in the generation of phosphine as it was the source of for the reaction P --> PH3. |
6(0,0,1,1) | Details |
| 17985877 | Mathew J, Thomas T, Suresh CH: Quantitative assessment of the stereoelectronic profile of phosphine ligands. Inorg Chem. 2007 Dec 10;46(25):10800-9. Epub 2007 Nov 7. The difference between the Vmin of unsubstituted PH3 (Vmin (PH3)) and the Vmin of PR3 is considered as Eeff + Seff. |
3(0,0,0,3) | Details |
| 17456261 | Funke HH, Raynor MW, Bertness KA, Chen Y: Detection of trace water vapor in high-purity phosphine using cavity ring-down spectroscopy. Appl Spectrosc. 2007 Apr;61(4):419-23. A commercial cavity ring-down spectrometer that monitors an absorption line at a wavelength of 1392.53 nm was investigated for service in high purity PH3. |
3(0,0,0,3) | Details |
| 17632740 | Karhanek D, Kacer P, Kuzma M, Splichalova J, Cerveny L: The platinum-olefin binding energy in series of (PH3) 2Pt (olefin) complexes--a theoretical study. J Mol Model. 2007 Sep;13(9):1009-16. Epub 2007 Jul 14. Theoretical investigation of Pt (0)-olefin organometallic complexes containing tertiary phosphine ligands was focused on the strength of platinum-olefin electronic interaction. |
2(0,0,0,2) | Details |
| 16718337 | Llewellyn SA, Green ML, Green JC, Cowley AR: Migratory insertion in N-heterocyclic carbene-containing Fe carbonyl complexes: an experimental and theoretical study. Dalton Trans. 2006 Jun 7;(21):2535-41. Epub 2006 Mar 17. The alkyl and acyl derivatives exist in an equilibrium that is more easily perturbed than in the tertiary phosphine analogues. DFT studies on the reactivity of [Fe (eta-C5H5)(CO) 2 (Me)] with PH3 and dihydroimidazole-2-ylidene (IH) have shown that CO exchange is energetically favoured for IH, and energetically disfavoured for PH3. |
2(0,0,0,2) | Details |
| 16780319 | Suresh CH: Molecular electrostatic potential approach to determining the steric effect of phosphine ligands in organometallic chemistry. Inorg Chem. 2006 Jun 26;45(13):4982-6. A two-layer ONIOM (B3LYP/6-31G (d,p):UFF) quantum mechanics (QM)-molecular mechanics (MM) optimization of PR3 ligands, where the QM layer is always constructed as PH3, followed by molecular electrostatic potential (MESP) analysis of the QM layer is suggested as a simple and effective method for evaluating the steric effect of PR3 ligands. |
2(0,0,0,2) | Details |
| 17256509 | Zhu R, Kong D, Sun L, Geng J, Wang X, Glindemann D: Tropospheric phosphine and its sources in coastal antarctica. Environ Sci Technol. 2006 Dec 15;40(24):7656-61. Our air sampling sites are located downwind of two large penguin colonies, indicating that penguin colony emission is the predominant source for atmospheric PH3 on Millor Peninsula. |
2(0,0,0,2) | Details |
| 18950169 | Erhardt S, Macgregor SA: Computational study of the reaction of C6F6 with [IrMe (PEt3) 3]: identification of a phosphine-assisted C-F activation pathway via a metallophosphorane intermediate. J Am Chem Soc. 2008 Nov 19;130(46):15490-8. Epub 2008 Oct 25. Using a model species, trans-[IrMe (PH3) 2 (PH2Et)], a low-energy mechanism involving nucleophilic attack of the electron-rich Ir metal center at C6F6 with displacement of has been identified. |
1(0,0,0,1) | Details |
| 19566158 | Nikitin AV, Holka F, Tyuterev VG, Fremont J: Vibration energy levels of the PH3, PH2D, and PHD2 molecules calculated from high order potential energy surface. J Chem Phys. 2009 Jun 28;130(24):244312. The grid of 11,697 geometrical nuclear configurations covers a large domain of the six dimensional internal coordinate space and was designed to provide vibration energy levels of phosphine molecule up to 7000 cm (-1) above the zero point vibration energy with reasonable accuracy. |
1(0,0,0,1) | Details |
| 18823113 | Jacobsen H, Donahue JP: Computational study of iron bis (dithiolene) complexes: redox non-innocent ligands and antiferromagnetic coupling. Inorg Chem. 2008 Nov 3;47(21):10037-45. Epub 2008 Sep 30. The molecular and electronic structure of monomeric ([Fe (S2C2H2) 2](z), [Fe (S2C2 (C6H4-p-OCH3) 2) 2](z)) and dimeric ([{Fe (S2C2H2) 2}2](z)) iron bis (dithiolene) complexes, and of their phosphine adducts ([(PH3) Fe (S2C2H2) 2](z), [(P (C6H5) 3) Fe (S2C2H2) 2](z), [(PH3) Fe (S2C2 (C6H4-p-OCH3) 2) 2](z)), carrying various charges (z = 0, 1-, 2-), have been investigated by density functional theory (DFT). |
81(1,1,1,1) | Details |
| 15698643 | Ding L, Wang X, Zhu Y, Edwards M, Glindemann D, Ren H: Effect of pH on phosphine production and the fate of during anaerobic process with granular sludge. Chemosphere. 2005 Mar;59(1):49-54. The maximum concentration of matrix-bound phosphine of 3.30 ng PH3 kg-1 wet sludge was achieved at pH 6. |
38(0,1,2,3) | Details |
| 16277441 | Wang Y, Lew KK, Ho TT, Pan L, Novak SW, Dickey EC, Redwing JM, Mayer TS: Use of phosphine as an n-type dopant source for vapor-liquid-solid growth of nanowires. Nano Lett. 2005 Nov;5(11):2139-43. Phosphine (PH3) was investigated as an n-type dopant source for Au-catalyzed vapor-liquid-solid (VLS) growth of -doped nanowires (SiNWs). |
34(0,1,1,4) | Details |
| 12700416 | Cheng Q, Valmas N, Reilly PE, Collins PJ, Kopittke R, Ebert PR: Caenorhabditis elegans mutants resistant to phosphine toxicity show increased longevity and cross-resistance to the synergistic action of Toxicol Sci. 2003 May;73(1):60-5. Epub 2003 Apr 15. Phosphine phosphide, PH3) is the fumigant most widely used to protect stored products from pest infestation. |
31(0,1,1,1) | Details |