Protein Information

Name PF6
Synonyms PF6; Projection protein PF6; RP4 776P7.2; SPAG17; sperm associated antigen 17; Projection protein PF6s; sperm associated antigen 17s

Compound Information

Name naphthalene
CAS naphthalene

Reference List

PubMed Abstract RScore(About this table)
17441109 Khoshbin MS, Ovchinnikov MV, Salaita KS, Mirkin CA, Stern CL, Zakharov LN, Rheingold AL: Metallomacrocycles that incorporate cofacially aligned diimide units. Chem Asian J. 2006 Nov 20;1(5):686-92.

Pyromellitic diimide and naphthalene diimide moieties were incorporated into hemilabile phosphanylalkyl thioether ligands.
These ligands reacted with [Cu (CH3CN) 4] PF6 and [Rh (NBD) Cl] 2 (NBD = norbornadiene) by the weak-link approach to form condensed intermediates.
1(0,0,0,1) Details
17140241 Pilloni G, Toffoletti A, Bandoli G, Longato B: Homoleptic complexes of cobalt (0) and nickel (0,I) with 1,1'-bis (diphenylphosphino) ferrocene (dppf): synthesis and characterization. Inorg Chem. 2006 Dec 11;45(25):10321-8.

Reduction of Ni (dppf) Cl2 with sodium in the presence of dppf and catalytic amounts of naphthalene affords Ni (dppf) 2, 3, isolated in 60% yield as a yellow air stable solid.
The stoichiometric oxidation of 3 with [FeCp2] PF6 forms the d9 complex [Ni (dppf) 2] PF6, 4, which represents the second example of a structurally characterized Ni (I) complex stabilized by phosphines.
1(0,0,0,1) Details
19927819 Dai N, Zhang FJ, Chen J, Mu H, Li S, Lu RS: [Preparation of solvent impregnated resin with [omim] [PF6] and mechanism of adsorpting naphthalene]. Huan Jing Ke Xue. 2009 Sep 15;30(9):2641-6.
88(1,1,2,3) Details
17134289 Labonne A, Kribber T, Hintermann L: Highly active in situ catalysts for anti-Markovnikov hydration of terminal alkynes. Org Lett. 2006 Dec 7;8(25):5853-6.

The anti-Markovnikov hydration of terminal alkynes to give aldehydes is catalyzed by complexes derived in situ from air-stable [CpRu (eta6-naphthalene)] PF6 (C) and 6-aryl-2-diphenylphosphinopyridines (L).
31(0,1,1,1) Details